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CO, N, and CO/N mixed gas injection for enhanced shale gas recovery and CO geological storage

《能源前沿（英文）》 2023年 第17卷 第3期   页码 428-445 doi: 10.1007/s11708-023-0865-9

摘要： In this work, using fractured shale cores, isothermal adsorption experiments and core flooding tests were conducted to investigate the performance of injecting different gases to enhance shale gas recovery and CO2 geological storage efficiency under real reservoir conditions. The adsorption process of shale to different gases was in agreement with the extended-Langmuir model, and the adsorption capacity of CO2 was the largest, followed by CH4, and that of N2 was the smallest of the three pure gases. In addition, when the CO2 concentration in the mixed gas exceeded 50%, the adsorption capacity of the mixed gas was greater than that of CH4, and had a strong competitive adsorption effect. For the core flooding tests, pure gas injection showed that the breakthrough time of CO2 was longer than that of N2, and the CH4 recovery factor at the breakthrough time (RCH4) was also higher than that of N2. The RCH4 of CO2 gas injection was approximately 44.09%, while the RCH4 of N2 was only 31.63%. For CO2/N2 mixed gas injection, with the increase of CO2 concentration, the RCH4 increased, and the RCH4 for mixed gas CO2/N2 = 8:2 was close to that of pure CO2, about 40.24%. Moreover, the breakthrough time of N2 in mixed gas was not much different from that when pure N2 was injected, while the breakthrough time of CO2 was prolonged, which indicated that with the increase of N2 concentration in the mixed gas, the breakthrough time of CO2 could be extended. Furthermore, an abnormal surge of N2 concentration in the produced gas was observed after N2 breakthrough. In regards to CO2 storage efficiency (Sstorage-CO2), as the CO2 concentration increased, Sstorage-CO2 also increased. The Sstorage-CO2 of the pure CO2 gas injection was about 35.96%, while for mixed gas CO2/N2 = 8:2, Sstorage-CO2 was about 32.28%.

关键词： shale gas     gas injection     competitive adsorption     enhanced shale gas recovery     CO2 geological storage    

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凝析气藏的经济开采模式

刘廷元

《中国工程科学》 2001年 第3卷 第3期   页码 85-91

摘要：

液态凝析油是凝析气藏的重要产品，它的开采应该是有效而经济的。介绍了国外近20 a来在凝析气藏开采技术领域的各种经济模式，包括回注φd=75%干气、自流回注、注N2、注水、水气交替注和注CO2等开采模式。研究结果表明，这些开采模式同传统的降压开采方法相比，能够有效地适应地面-地下的各种复杂情况。

关键词： 凝析气藏     开采模式     注气     注氮     注水     注二氧化碳     经济    

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气辅注塑成型注气压力的模糊神经网络控制研究

欧长劲

《中国工程科学》 2007年 第9卷 第5期   页码 27-32

摘要：

针对气辅注塑成形的注气压力精确控制要求，设计了具有５层结构的模糊神经网络控制器和控制算法，利用神经网络的学习能力实现对模糊逻辑规则的优化，改善了系统的适应性。对系统３段压力控制的仿真 分析，验证了模糊神经网络控制模型的可行性，控制效果良好。

关键词： 气体辅助注射成型     模糊神经网络     注气压力控制    

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Development of a simplified n-heptane/methane model for high-pressure direct-injection naturalgas marine engines

Jingrui LI, Haifeng LIU, Xinlei LIU, Ying YE, Hu WANG, Xinyan WANG, Hua ZHAO, Mingfa YAO

《能源前沿（英文）》 2021年 第15卷 第2期   页码 405-420 doi: 10.1007/s11708-021-0718-3

摘要： High-pressure direct-injection (HPDI) of natu-ral gas is one of the most promising solutions for future ship engines, in which the combustion process is mainly controlled by the chemical kinetics. However, the employment of detailed chemical models for the multi-dimensional combustion simulation is significantly expensive due to the large scale of the marine engine. In the present paper, a reduced -heptane/methane model consisting of 35-step reactions was constructed using multiple reduction approaches. Then this model was further reduced to include only 27 reactions by utilizing the HyChem (Hybrid Chemistry) method. An overall good agreement with the experimentally measured ignition delay data of both -heptane and methane for these two reduced models was achieved and reasonable predictions for the measured laminar flame speeds were obtained for the 35-step model. But the 27-step model cannot predict the laminar flame speed very well. In addition, these two reduced models were both able to reproduce the experimentally measured in-cylinder pressure and heat release rate profiles for a HPDI natural gas marine engine, the highest error of predicted combustion phase being 6.5%. However, the engine-out CO emission was over-predicted and the highest error of predicted NO emission was less than 12.9%. The predicted distributions of temperature and equivalence ratio by the 35-step and 27-step models are similar to those of the 334-step model. However, the predicted distributions of OH and CH O are significantly different from those of the 334-step model. In short, the reduced chemical kinetic models developed provide a high-efficient and dependable method to simulate the characteristics of combustion and emissions in HPDI natural gas marine engines.

关键词： high-pressure direct-injection     natural gas     chemical kinetics     combustion modelling     marine engine    

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semi-volatile organic compounds in water using automated online solid-phase extraction with large-volume injection/gas chromatography/mass spectrometry

Yongtao LI, Christina L. MCCARTY, Ed J. GEORGE

《环境科学与工程前沿（英文）》 2011年 第5卷 第3期   页码 417-425 doi: 10.1007/s11783-011-0310-x

摘要： A rapid, sensitive, and cost-effective analytical method was developed for the analysis of selected semi-volatile organic compounds in water. The method used an automated online solid-phase extraction technique coupled with programmed-temperature vaporization large-volume injection gas chromatography/mass spectrometry. The water samples were extracted by using a fully automated mobile rack system based on x-y-z robotic techniques using syringes and disposable 96-well extraction plates. The method was validated for the analysis of 30 semi-volatile analytes in drinking water, groundwater, and surface water. For a sample volume of 10 mL, the linear calibrations ranged from 0.01 or 0.05 to 2.5μg·L , and the method detection limits were less than 0.1μg·L . For the reagent water samples fortified at 1.0μg·L and 2.0?μg·L , the obtained mean absolute recoveries were 70%–130% with relative standard deviations of less than 20% for most analytes. For the drinking water, groundwater, and surface water samples fortified at 1.0μg·L , the obtained mean absolute recoveries were 50%–130% with relative standard deviations of less than 20% for most analytes. The new method demonstrated three advantages: 1) no manipulation except the fortification of surrogate standards prior to extraction; 2) significant cost reduction associated with sample collection, shipping, storage, and preparation; and 3) reduced exposure to hazardous solvents and other chemicals. As a result, this new automated method can be used as an effective approach for screening and/or compliance monitoring of selected semi-volatile organic compounds in water.

关键词： automated solid-phase extraction     programmed-temperature vaporization     large-volume injection     gas chromatography/mass spectrometry     semi-volatile organic compounds     water analysis    

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Effect of ignition timing and hydrogen fraction on combustion and emission characteristics of natural gasdirect-injection engine

WANG Jinhua, HUANG Zuohua, LIU Bing, ZENG Ke, YU Jinrong, JIANG Deming

《能源前沿（英文）》 2008年 第2卷 第2期   页码 194-201 doi: 10.1007/s11708-008-0035-0

摘要： An experimental study on the combustion and emission characteristics of a direct-injection spark-ignited engine fueled with natural gas/hydrogen blends under various ignition timings was conducted. The results show that ignition timing has a significant influence on engine performance, combustion and emissions. The interval between the end of fuel injection and ignition timing is a very important parameter for direct-injection natural gas engines. The turbulent flow in the combustion chamber generated by the fuel jet remains high and relative strong mixture stratification is introduced when decreasing the angle interval between the end of fuel injection and ignition timing giving fast burning rates and high thermal efficiencies. The maximum cylinder gas pressure, maximum mean gas temperature, maximum rate of pressure rise and maximum heat release rate increase with the advancing of ignition timing. However, these parameters do not vary much with hydrogen addition under specific ignition timing indicating that a small hydrogen fraction addition of less than 20% in the present experiment has little influence on combustion parameters under specific ignition timing. The exhaust HC emission decreases while the exhaust CO concentration increases with the advancing of ignition timing. In the lean combustion condition, the exhaust CO does not vary much with ignition timing. At the same ignition timing, the exhaust HC decreases with hydrogen addition while the exhaust CO and CO do not vary much with hydrogen addition. The exhaust NO increases with the advancing of ignition timing and the behavior tends to be more obvious at large ignition advance angle. The brake mean effective pressure and the effective thermal efficiency of natural gas/hydrogen mixture combustion increase compared with those of natural gas combustion when the hydrogen fraction is over 10%.
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气辅成型工艺参数对制品成型质量的影响趋势研究

邱水金,姜少飞 ,柴国钟,鲁聪达

《中国工程科学》 2009年 第11卷 第4期   页码 84-90

摘要：

对截面形状为s-3的加强筋进行工艺参数优化分析，讨论了气辅成型工艺参数对成型质量的影响程度，获得了一组较好的工艺参数组合。以此为参考标准，改变某一个工艺参数而保持其他工艺参数不变，对比研究4种不同截面形状加强筋在气辅成型条件下的成型情况，并考察了单个工艺参数对成型质量的影响趋势情况。

关键词： 气体辅助注射成型     加强筋     正交试验设计    

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喷射策略对低负荷下天然气——柴油双燃料预混压燃燃烧的影响研究 Article

Hyunwook Park, Euijoon Shim, Choongsik Bae

《工程（英文）》 2019年 第5卷 第3期   页码 548-557 doi: 10.1016/j.eng.2019.03.005

摘要：

双燃料预混压燃（dual-fuel premixed charge compression ignition, DF-PCCI）燃烧因其氮氧化物（NOx）和颗粒物（PM）排放低而被认为是重载压燃发动机中传统柴油燃烧的可行替代方案。当天然气（NG）应用于DF-PCCI发动机时，其低反应活性降低了高负荷下的最大压升率。然而，天然气- 柴油DF-PCCI发动机在低负荷工况运行时存在燃烧效率低的问题。为了降低低负荷工况下的燃料消耗率、未燃碳氢化合物（HC）和一氧化碳（CO）排放，本文研究了DF-PCCI发动机中供给燃料（天然气和柴油）的喷射策略。研究发现，天然气替代率和柴油喷射时刻（start of energizing, SOE）的改变有效地控制了燃料- 空气混合气的形成。采用柴油两次喷射策略可以调节混合气的局部反应活性。预喷柴油SOE 的延迟和预喷柴油喷射量的减少有利于降低燃烧损失。废气再循环（EGR）的引入通过推迟燃烧相位改善了燃料经济性并将NOx 和PM 排放降低至欧六（Euro Ⅵ）标准以下。结合40％天然气替代率，柴油两次喷射策略和中等EGR 率可以在低负荷工况下有效提高燃烧效率与指示效率，并降低HC和CO排放。

关键词： 双燃料     反应可控压燃     预混压燃     天然气     喷射策略     废气再循环    

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Laboratory study on high-temperature adsorption of HCl by dry-injection of Ca(OH)

Junjun TAN,Guohua YANG,Jingqiao MAO,Huichao DAI

《环境科学与工程前沿（英文）》 2014年 第8卷 第6期   页码 863-870 doi: 10.1007/s11783-013-0618-9

摘要： Combustion-generated hydrogen chloride (HCl) is considered to be a very hazardous acid gaseous pollutant. This paper presents a laboratory study on the dry adsorption of HCl. The experiments were conducted in a dual-layer granular bed filter, at gas temperatures of 500°C–700°C and (Ca)/ (Cl)molar ratios of 1.0–5.0 using the silver nitrate titration method by dry adsorbent powders Ca(OH) . Mainly, the adsorption efficiency of HCl and utilization efficiency of Calcium were studied, by varying relevant factors including (Ca)/ (Cl), temperature, feeding method, water vapor and CO . With a relatively higher HCl concentration of 1000 ppm, the experimental results revealed that 600°C may be the optimum temperature for HCl adsorption when optimum (Ca)/ (Cl) was 2.5 in our tests. The results also demonstrated that the feeding at a constant pressure was more effective, and the HCl adsorption efficiency could rapidly reach over 90% with (Ca)/ (Cl) = 2.5 at 600°C. Furthermore, the HCl adsorption efficiency was found to be slightly promoted by water vapor, while could be impeded by CO , and the utilization efficiency of calcium could be up to 74.4% without CO , while was only 36.8% with CO when (Ca)/ (Cl) was 2.5 at 600°C.

关键词： acid gas HCl     Ca(OH)2     dry adsorption     high temperature     dual-layer granular bed filter    

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Three-dimensional numerical simulation for plastic injection-compression molding

Yun ZHANG, Wenjie YU, Junjie LIANG, Jianlin LANG, Dequn LI

《机械工程前沿（英文）》 2018年 第13卷 第1期   页码 74-84 doi: 10.1007/s11465-018-0490-1

摘要：

Compared with conventional injection molding, injection-compression molding can mold optical parts with higher precision and lower flow residual stress. However, the melt flow process in a closed cavity becomes more complex because of the moving cavity boundary during compression and the nonlinear problems caused by non-Newtonian polymer melt. In this study, a 3D simulation method was developed for injection-compression molding. In this method, arbitrary Lagrangian-Eulerian was introduced to model the moving-boundary flow problem in the compression stage. The non-Newtonian characteristics and compressibility of the polymer melt were considered. The melt flow and pressure distribution in the cavity were investigated by using the proposed simulation method and compared with those of injection molding. Results reveal that the fountain flow effect becomes significant when the cavity thickness increases during compression. The back flow also plays an important role in the flow pattern and redistribution of cavity pressure. The discrepancy in pressures at different points along the flow path is complicated rather than monotonically decreased in injection molding.

关键词： injection-compression molding     simulation     injection molding     melt flow     cavity pressure    

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density measurement for plastic injection molding via ultrasonic technology

《机械工程前沿（英文）》 2022年 第17卷 第4期 doi: 10.1007/s11465-022-0714-2

摘要： Density variation during the injection molding process directly reflects the state of plastic melt and contains valuable information for process monitoring and optimization. Therefore, in-situ density measurement is of great interest and has significant application value. The existing methods, such as pressure−volume−temperature (PVT) method, have the shortages of time-delay and high cost of sensors. This study is the first to propose an in-situ density measurement method using ultrasonic technology. The analyses of the time-domain and frequency-domain signals are combined in the proposed method. The ultrasonic velocity is obtained from the time-domain signals, and the acoustic impedance is computed through a full-spectral analysis of the frequency-domain signals. Experiments with different process conditions are conducted, including different melt temperature, injection speed, material, and mold structure. Results show that the proposed method has good agreement with the PVT method. The proposed method has the advantages of in-situ measurement, non-destructive, high accuracy, low cost, and is of great application value for the injection molding industry.

关键词： ultrasonic measurement     melt density     in-situ measurement     injection molding    

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Trend prediction technology of condition maintenance for large water injection units

Xiaoli XU, Sanpeng DENG

《机械工程前沿（英文）》 2010年 第5卷 第2期   页码 171-175 doi: 10.1007/s11465-009-0091-0

摘要： Trend prediction technology is the key technology to achieve condition-based maintenance of mechanical equipment. Large-sized water injection units are key equipment in oilfields. The traditional preventive maintenance is not economical and cannot completely avoid vicious accidents. To ensure the normal operation of units and save maintenance costs, trend prediction technology is studied to achieve condition-based maintenance for water injection units. The main methods of the technology are given, the trend prediction method based on neural network is put forward, and the expert system based on the knowledge is developed. The industrial site verification shows that the proposed trend prediction technology can reflect the operating condition trend change of the water injection units and provide technical means to achieve condition-based predictive maintenance.

关键词： water injection units     condition-based maintenance     trend prediction    

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Intelligent methods for the process parameter determination of plastic injection molding

Huang GAO, Yun ZHANG, Xundao ZHOU, Dequn LI

《机械工程前沿（英文）》 2018年 第13卷 第1期   页码 85-95 doi: 10.1007/s11465-018-0491-0

摘要：

Injection molding is one of the most widely used material processing methods in producing plastic products with complex geometries and high precision. The determination of process parameters is important in obtaining qualified products and maintaining product quality. This article reviews the recent studies and developments of the intelligent methods applied in the process parameter determination of injection molding. These intelligent methods are classified into three categories: Case-based reasoning methods, expert system-based methods, and data fitting and optimization methods. A framework of process parameter determination is proposed after comprehensive discussions. Finally, the conclusions and future research topics are discussed.

关键词： injection molding     intelligent methods     process parameters     optimization    

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methodology for regulating fuel stratification and improving fuel economy of GCI mode via double main-injection

《能源前沿（英文）》 2023年 第17卷 第5期   页码 678-691 doi: 10.1007/s11708-022-0859-z

摘要： Gasoline compression ignition (GCI) combustion faces problems such as high maximum pressure rise rate (MPRR) and combustion deterioration at high loads. This paper aims to improve the engine performance of the GCI mode by regulating concentration stratification and promoting fuel-gas mixing by utilizing the double main-injection (DMI) strategy. Two direct injectors simultaneously injected gasoline with an octane number of 82.7 to investigate the energy ratio between the two main-injection and exhaust gas recirculation (EGR) on combustion and emissions. High-load experiments were conducted using the DMI strategy and compared with the single main-injection (SMI) strategy and conventional diesel combustion. The results indicate that the DMI strategy have a great potential to reduce the MPRR and improve the fuel economy of the GCI mode. At a 10 bar indicated mean effective pressure, increasing the main-injection-2 ratio (Rm-2) shortens the injection duration and increases the mean mixing time. Optimized Rm-2 could moderate the trade-off between the MPRR and the indicated specific fuel consumption with both reductions. An appropriate EGR should be adopted considering combustion and emissions. The DMI strategy achieves a highly efficient and stable combustion at high loads, with an indicated thermal efficiency (ITE) greater than 48%, CO and THC emissions at low levels, and MPRR within a reasonable range. Compared with the SMI strategy, the maximum improvement of the ITE is 1.5%, and the maximum reduction of MPRR is 1.5 bar/°CA.

关键词： gasoline compression ignition     injection strategy     fuel stratification     high efficiency     high load    

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Experimental study of stratified lean burn characteristics on a dual injection gasoline engine

Chun XIA, Tingyu ZHAO, Junhua FANG, Lei ZHU, Zhen HUANG

《能源前沿（英文）》 2022年 第16卷 第6期   页码 900-915 doi: 10.1007/s11708-021-0812-6

摘要： Due to increasingly stringent fuel consumption and emission regulation, improving thermal efficiency and reducing particulate matter emissions are two main issues for next generation gasoline engine. Lean burn mode could greatly reduce pumping loss and decrease the fuel consumption of gasoline engines, although the burning rate is decreased by higher diluted intake air. In this study, dual injection stratified combustion mode is used to accelerate the burning rate of lean burn by increasing the fuel concentration near the spark plug. The effects of engine control parameters such as the excess air coefficient (Lambda), direct injection (DI) ratio, spark interval with DI, and DI timing on combustion, fuel consumption, gaseous emissions, and particulate emissions of a dual injection gasoline engine are studied. It is shown that the lean burn limit can be extended to Lambda= 1.8 with a low compression ratio of 10, while the fuel consumption can be obviously improved at Lambda= 1.4. There exists a spark window for dual injection stratified lean burn mode, in which the spark timing has a weak effect on combustion. With optimization of the control parameters, the brake specific fuel consumption (BSFC) decreases 9.05% more than that of original stoichiometric combustion with DI as 2 bar brake mean effective pressure (BMEP) at a 2000 r/min engine speed. The NOx emissions before three-way catalyst (TWC) are 71.31% lower than that of the original engine while the particle number (PN) is 81.45% lower than the original engine. The dual injection stratified lean burn has a wide range of applications which can effectively reduce fuel consumption and particulate emissions. The BSFC reduction rate is higher than 5% and the PN reduction rate is more than 50% with the speed lower than 2400 r/min and the load lower than 5 bar.

关键词： dual injection     stratified lean burn     gasoline engine     particulate matter emission     combustion analysis    

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标题 作者 时间 类型 操作

CO, N, and CO/N mixed gas injection for enhanced shale gas recovery and CO geological storage

期刊论文

凝析气藏的经济开采模式

刘廷元

期刊论文

气辅注塑成型注气压力的模糊神经网络控制研究

欧长劲

期刊论文

Development of a simplified n-heptane/methane model for high-pressure direct-injection naturalgas marine engines

Jingrui LI, Haifeng LIU, Xinlei LIU, Ying YE, Hu WANG, Xinyan WANG, Hua ZHAO, Mingfa YAO

期刊论文

semi-volatile organic compounds in water using automated online solid-phase extraction with large-volume injection/gas chromatography/mass spectrometry

Yongtao LI, Christina L. MCCARTY, Ed J. GEORGE

期刊论文

Effect of ignition timing and hydrogen fraction on combustion and emission characteristics of natural gasdirect-injection engine

WANG Jinhua, HUANG Zuohua, LIU Bing, ZENG Ke, YU Jinrong, JIANG Deming

期刊论文

气辅成型工艺参数对制品成型质量的影响趋势研究

邱水金,姜少飞 ,柴国钟,鲁聪达

期刊论文

喷射策略对低负荷下天然气——柴油双燃料预混压燃燃烧的影响研究

Hyunwook Park, Euijoon Shim, Choongsik Bae

期刊论文

Laboratory study on high-temperature adsorption of HCl by dry-injection of Ca(OH)

Junjun TAN,Guohua YANG,Jingqiao MAO,Huichao DAI

期刊论文

Three-dimensional numerical simulation for plastic injection-compression molding

Yun ZHANG, Wenjie YU, Junjie LIANG, Jianlin LANG, Dequn LI

期刊论文

density measurement for plastic injection molding via ultrasonic technology

期刊论文

Trend prediction technology of condition maintenance for large water injection units

Xiaoli XU, Sanpeng DENG

期刊论文

Intelligent methods for the process parameter determination of plastic injection molding

Huang GAO, Yun ZHANG, Xundao ZHOU, Dequn LI

期刊论文

methodology for regulating fuel stratification and improving fuel economy of GCI mode via double main-injection

期刊论文

Experimental study of stratified lean burn characteristics on a dual injection gasoline engine

Chun XIA, Tingyu ZHAO, Junhua FANG, Lei ZHU, Zhen HUANG

期刊论文